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Key Points We re‐evaluate equations proposed by Francis Hall to assess concentration‐discharge ( C ‐ Q ) relationships using newly available long‐term and high‐frequency data sets Across time steps we find that log‐log and log‐linear models perform equally well to describe C ‐ Q relationships Parametrization of storage‐discharge relationships via recession analyses provides additional insight to C ‐ Q relationships 

The concurrent reduction in acid deposition and increase in precipitation impact stream solute dynamics in complex ways that make predictions of future water quality difficult. To understand how changes in acid deposition and precipitation have influenced dissolved organic carbon (DOC) and nitrogen (N) loading to streams, we investigated trends from 1991 to 2018 in stream concentrations (DOC, ~3,800 measurements), dissolved organic nitrogen (DON, ~1,160 measurements), and dissolved inorganic N (DIN, ~2,130 measurements) in a forested watershed in Vermont, USA. Our analysis included concentration-discharge (C-Q) relationships and Seasonal Mann-Kendall tests on long-term, flow-adjusted concentrations. To understand whether hydrologic flushing and changes in acid deposition influenced long-term patterns by liberating DOC and dissolved N from watershed soils, we measured their concentrations in the leachate of 108 topsoil cores of 5 cm diameter that we flushed with solutions simulating high and low acid deposition during four different seasons. Our results indicate that DOC and DON often co-varied in both the long-term stream dataset and the soil core experiment. Additionally, leachate from winter soil cores produced especially high concentrations of all three solutes. This seasonal signal was consistent with C-Q relation showing that organic materials (e.g., DOC and DON), which accumulate during winter, are flushed into streams during spring snowmelt. Acid deposition had opposite effects on DOC and DON compared to DIN in the soil core experiment. Low acid deposition solutions, which mimic present day precipitation, produced the highest DOC and DON leachate concentrations. Conversely, high acid deposition solutions generally produced the highest DIN leachate concentrations. These results are consistent with the increasing trend in stream DOC concentrations and generally decreasing trend in stream DIN we observed in the long-term data. These results suggest that the impact of acid deposition on the liberation of soil carbon (C) and N differed for DOC and DON vs. DIN, and these impacts were reflected in long-term stream chemistry patterns. As watersheds continue to recover from acid deposition, stream C:N ratios will likely continue to increase, with important consequences for stream metabolism and biogeochemical processes. 

Abstract Winters in snow-covered regions have warmed, likely shifting the timing and magnitude of nutrient export, leading to unquantified changes in water quality. Intermittent, seasonal, and permanent snow covers more than half of the global land surface. Warming has reduced the cold conditions that limit winter runoff and nutrient transport, while cold season snowmelt, the amount of winter precipitation falling as rain, and rain-on-snow have increased. We used existing geospatial datasets (rain-on-snow frequency overlain on nitrogen and phosphorous inventories) to identify areas of the contiguous United States (US) where water quality could be threatened by this change. Next, to illustrate the potential export impacts of these events, we examined flow and turbidity data from a large regional rain-on-snow event in the United States’ largest river basin, the Mississippi River Basin. We show that rain-on-snow, a major flood-generating mechanism for large areas of the globe (Berghuijs et al 2019 Water Resour. Res. 55 4582–93; Berghuijs et al 2016 Geophys. Res. Lett. 43 4382–90), affects 53% of the contiguous US and puts 50% of US nitrogen and phosphorus pools (43% of the contiguous US) at risk of export to groundwater and surface water. Further, the 2019 rain-on-snow event in the Mississippi River Basin demonstrates that these events could have large, cascading impacts on winter nutrient transport. We suggest that the assumption of low wintertime discharge and nutrient transport in historically snow-covered regions no longer holds. Critically, however, we lack sufficient data to accurately measure and predict these episodic and potentially large wintertime nutrient export events at regional to continental scales. 

Abstract Extreme events have increased in frequency globally, with a simultaneous surge in scientific interest about their ecological responses, particularly in sensitive freshwater, coastal, and marine ecosystems. We synthesized observational studies of extreme events in these aquatic ecosystems, finding that many studies do not use consistent definitions of extreme events. Furthermore, many studies do not capture ecological responses across the full spatial scale of the events. In contrast, sampling often extends across longer temporal scales than the event itself, highlighting the usefulness of long-term monitoring. Many ecological studies of extreme events measure biological responses but exclude chemical and physical responses, underscoring the need for integrative and multidisciplinary approaches. To advance extreme event research, we suggest prioritizing pre- and postevent data collection, including leveraging long-term monitoring; making intersite and cross-scale comparisons; adopting novel empirical and statistical approaches; and developing funding streams to support flexible and responsive data collection. 

Processes that drive variability in catchment solute sourcing, transformation, and transport can be investigated using concentration–discharge (C–Q) relationships. These relationships reflect catchment and in‐stream processes operating across nested temporal scales, incorporating both short and long‐term patterns. Scientists can therefore leverage catchment‐scale C–Q datasets to identify and distinguish among the underlying meteorological, biological, and geological processes that drive solute export patterns from catchments and influence the shape of their respective C–Q relationships. We have synthesized current knowledge regarding the influence of biological, geological, and meteorological processes on C–Q patterns for various solute types across diel to decadal time scales. We identify cross‐scale linkages and tools researchers can use to explore these interactions across time scales. Finally, we identify knowledge gaps in our understanding of C–Q temporal dynamics as reflections of catchment and in‐stream processes. We also lay the foundation for developing an integrated approach to investigate cross‐scale linkages in the temporal dynamics of C–Q relationships, reflecting catchment biogeochemical processes and the effects of environmental change on water quality.

This article is categorized under:

Science of Water > Hydrological Processes

Science of Water > Water Quality

Science of Water > Water and Environmental Change

 

While many instructors have reservations against Wikipedia use in academic settings, editing Wikipedia teaches students valuable writing, editing, and critical thinking skills. Wikipedia assignments align with the community of inquiry framework, which focuses on the elements needed for a successful online learning experience. We report on a faculty mentoring network, created by WikiProject Limnology and Oceanography, which helped 14 instructors with little to no prior experience implement a Wikipedia assignment in their classes. We found that Wikipedia assignments increase students’ motivation to produce high quality work and enhance their awareness of reliable scientific sources. Wikipedia assignments can be comparable to other writing assignments in length and complexity, but have a far wider audience than a traditional research paper. Participants in our mentoring network reported challenges with implementing this new type of assignment, and here, we share resources and solutions to those reported barriers. 

A paired‐catchment study began in 2000 to assess the hydrologic effects of high‐elevation development on Mt. Mansfield, Vermont's highest summit (1340 m). West Branch Little River drains 12.08 km²and encompasses a large ski resort. Adjacent Ranch Brook drains 9.83 km²of minimally disturbed second‐growth forest. The two catchments have similar elevation, aspect, surficial and bedrock geology, and vegetation. The resort was well established before this study, but it underwent a major expansion during the period 2004–2008. The expansion included new ski lifts and trails, a large hotel, roads and second home development, a 435 000‐m³snowmaking storage pond and a nine‐hole golf course, increasing the extent of cleared/open land from 17% to 24%. Runoff from the developed West Branch Little River catchment was 21% greater than Ranch Brook over the duration of the study, but varied widely each year from 10% to 42%. This high variability occurs both on the interannual and individual storm scales, and is consistent with expectations from future climate projections. Hydrologic variability is on the rise, as shown by an increase in stream flashiness in both catchments over the 20 years of our study. Resort expansion, which provided for stormwater management, had no discernible effect on the overall runoff difference nor the flow distribution at the scale of the catchments, but sedimentation, water quality impacts and localized erosion cannot be ruled out. Forest clearing, impervious and hardened surfaces, and skier‐compacted and machine‐made snow may all cause enhanced runoff. However, the greater runoff at West Branch, which occurs primarily during snowmelt and summer, may arise partly from greater precipitation capture in the complex mountain topography. Development pressure on the mountain landscape continues to mount, but managers may also need to consider the confounding effects of a changing climate.